A COMPUTER AUGMENTED STUDY: ELECTROMETRIC INVESTIGATION ON TERNARY COMPLEXES OF VITAL METAL IONS WITH HISTAMINE IN AQUEOUS SURFACTANT MEDIUM
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Keywords
Glycylglcine, Histamine, Triton X–100 (TX100), Ternary complexes.
Abstract
In human body Chemical speciation shows significant part in comprehension the biological and physiological partsof metal ions and ligands. This study has been revealed that the complexation of Glycylglycine and Histamine with crucial metal ions in Triton X–100 (TX100). The analysis has been carried out using potentiometric method and the outcomesachieved in this examination have been progressed via gran plot method, SCPHD and MINIQUAD75 is utilized for best fit chemical model and refinement of results. In this study effect of surfactant on ternary complexes stability constants, effect of influential parameters like concentration of acid, alkali, ligands and metal ions on the stability constants have been evaluated by conducted an experiment.MLXH2, ML2XH2 and MLX2H3complexes formed in the present study. Chemical problems were correlated by using the advanced principles of mathematics and fuzzy logic, which is called chemo metrics. Errors in correction factor, ligand concentration and metal concentration less on the stability constants of ternary complexes than other parameters like alkali and acids. Influence of surfactant on stability constants of ternary complexes and effect of surfactant on distribution of metal - ligand species were also explained
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1. Balakrishna,M., Srinivasa Rao,G., Ramanaiah,M., Nageswara Rao, G. and Rama Raju,B., 2017. pH metric investigation on Chemical Speciation of Co(II), Ni(II) And Cu(II) Complexes With 5-Hydroxysalicylic Acid In Urea-Water Mixtures, J. Indian Chem. Soc.,94, p.905-912. 2. Ramanaiah, M., Gowri Kumari, V. and Sailaja, B.B.V., 2016. Effect of Anionic Surfactant on the Protonation Equilibria of L-Phenylalanine and Maleic Acid. J. Indian Chem. Soc., 93, p.285-292. 3. Balakrishna, M. and Seetharm, P., 2020. Qualitative and Quantitative Analysis of Metals in Vital Withania Somnifera Medicinal Plant Using Inductively Coupled Plasma-Mass Spectroscopy, Plant Cell Biotechnology and Molecular Biology, 5, p.136-43. 4. Ramanaiah, M., Goutham Sri, S. and Sailaja, B.B.V., 2014. Stability of Binary Complexes of Pb(II), Cd(II) and Hg(II) with Maleic acid in TX100-Water Mixtures. Bull. Chem. Soc. Ethiopia. 28(3), p.383-391. 5. Bunton, C.A., Cerichelli, G., Ihara, Y. and Supulveda, L., 1979. J. Am. Chem. Soc., 101, p.2429. 6. Feakins, D., Neille, R.D.O. and Woghonie, W.E, J., 1983. Chem. Soc. Faraday Trans., 35, p.2289. 7. Gran, G., 1952. Determination of the equivalence point in potentiometric titrations. Part II, The Analyst, 77, p.661-671. 8. Gran, G., 1988. Equivalence volumes in potentiometric titrations, Anal Chim Acta, 206, p.111-123. 9. Gans P., Sabatini A. and Vacca A., 1976. Inorg. Chim.Acta., 18, p.237. 10. Nageswara Rao, Ch., Ramanaiah, M. and Sailaja, B.B.V., 2014. Influence of Dielectric Constant on Protonation Equilibria of Maleic Acid and L-Asparagine in Acetonitrile Water -Mixtures. Chem. Speciat. Bioavail., 26(4), p.266-272. 11. Ramanaiah, M.,Seetharam,P., Balakrishna,M. and Rama Raju,B., 2019. Potentiometric Studies of ComplexeEqulibria of CaII, MgII and ZnII with 5-Sulphosalicylic Acid in Cationic Micelles of CTAB, Heliyon, 2019, 5(8), p.e02157. 12. Balakrishna, M., Srinivasa, Rao G., Ramanaiah, M., Nageswara Rao, G. and Rama Raju B., 2017. Speciation studies of ternary complexes of Co(II), Ni(II), and Cu(II) with 5-Sulfosalicylic acid and 5-Hydroxysalicylic acid in urea-water mixtures. Resea. J. Phar. Tech., 10(11), p.3681-3686. 13. Ramanaiah,M., Gouthamsri,S., Balakrishna,M. and Rama Raju,B., 2017. Effect of Cationic Micelles of Cetyltrimethylammonium Bromide on Protonation Equilibria of Salicylic Acid Derivatives. J. Chilean Chem. Soc., 62(4), p.3677-3682. 14. Balakrishna, M., Ramanaiah, M., Ramakrishna, B., Jayanthi Rao, M. and Neeraja, R.2022. Inductively Coupled Plasma-Mass Spectroscopy: Machine Learning Screening Technique for Trace Elemental Concentrations in Hemidesmus Indicus, Annals of Forest Research, 65(1) p.4431-4445. 15. Ramanaiah,M., Gouthamsri,S., Balakrishna,M.,Rama Raju,B. and Sailaja,B.B.V., 2017. Effect of Nonionic Micelles of TritonX-100 on Protonation Equilibria of Salicylic Acid Derivatives. J. Indian Chem. Soc., 94, p.253-259. 16. Balakrishna, M. and Seetharm, P., 2021. Qualitative and Quantitative Evaluation of Trace Elements in Amaranthaceae Family Medicinal Plant Using ICP-MS, International Journal of Current Research and Reviews, 13(5), p.58-65. 17. Ramanaiah, M., Seetharam, P. and Sailaja, B.B.V., 2014. Chemical speciation of ternary complexes of Pb-II, Cd-II and Hg-II with L-phenylalanine and maleic acid in TX100-water mixtures,J. Ind. Chem. Soc., 91(6), p.1011-1020. 18. Gowri Kumari, V., Ramanaiah, M. and Sailaja, B.B.V., 2015. A Speciation of Binary Complexes of Co(II), Ni(II) and Cu(II) With L-Phenylalanine In Anionic Micellar Medium. Chem. Speciat. Bioavail., 27(3), p.121-126. 19. Ramanaiah, M., Nageswara Rao, Ch. and Sailaja, B.B.V., 2014. Study of Ternary Complex Stability Constants of PbII, CdII, and HgII with L-Phenylalanine and Maleic Acid in SDS–Water Mixtures. Proc. Nat. Acad. Sci., India,84(4), p.485-494. 20. Balakrishna, M. and Srinivasa Rao, G., 2017. Study of Ternary Complex Stability Constants of Co(II), Ni(II) and Cu(II) with 5-Sulfosalicylic acid and 5-Hydroxysalicylic acid in DMF-Water Mixtures, Res. J. Chem. Env., 21, p.20. 21. Ramanaiah, M. and Sailaja, B.B.V., 2014. Mixed Ligand Complex Formation Equilibria of Some Toxic metal Ions with L-Phenylalanine and Maleic Acid in CTAB-Water Mixtures. J. Indian Chem. Soc., 91, p.1649-1660. 22. Balakrishna, M., Ramanaiah, M., Nageswara Rao, G., Ramaraju, B. and Srinivasa Rao, G., 2017. Influence of Dielectric Constants on Protonation Equlibria of 5-Sulfo Salicylic Acid and 5- Hydroxy Salicylic Acid in Urea-Water Mixtures. J. Indian Chem. Soc., 94, p.37-45. 23. Ramanaiah, M. and Sailaja, B.B.V., 2014. Protonation Equilibria of L-Phenylalanine and Maleic Acid in Cationic Micellar Media. Chem. Speciat. Bioavail., 26(2), p.119-125. 24. Seetharam, P., Ramanaiah, M., and Sailaja, B.B.V., 2016. Protonation Equilibria of glycylglycine and Histamine in cationic micellar media, J. Ind. Chem. Soc., 93(8), p.929-936. 25. Ramanaiah, M., Goutham Sri, S. and Sailaja, B.B.V., 2014. Formation of Binary Complexes of Pb(II), Cd(II) and Hg(II) With Maleic acid in CTAB-Water Mixtures. Chem. Speciat. Bioavail.,26(4), p.231-239. 26. Seetharam, P., Ramanaiah, M., Sathish Mohan, B. and Sailaja, B. B. V., 2020. Surfactant Effect on Acido-Basic Equilibria of Glycylglycine and Histamine in Neutral Micellar Media, Res. J. Chem. Env., 24, p.57-62. 27. Ramanaiah, M. andSailaja, B.B.V., 2014. pH-metric Investigation on Binary Complexes of Pb(II), Cd(II) and Hg(II) with maleic acid In SLS-Water Mixtures. J. Indian Chem. soc., 91, p.639-645. 28. Nageswara Rao, Ch., Ramanaiah, M. and Sailaja, B.B.V., 2016. Speciation of Binary Complexes of Pb(II) and Cd(II) With L-Asparagine in Dimethyl sulfoxide Medium. Bull. Chem. Soc. Ethiop. 30(1), p.71-78. 29. Ramanaiah, M. and Sailaja, B.B.V., 2014. pH-metric Investigation on Binary Complexes of Pb(II), Cd(II) and Hg(II) with maleic acid In SLS-Water Mixtures. J. Indian Chem. soc., 91, p.639-645. 30. Seetharam, P., Balakrishna, M., Sathish Mohan, B., Satyanarayana, G. and Sailaja, B. B. V., 2021. Potentiometric studies on Bioactive Material Species of Ternary Complexes, Russian Journal of General Chemistry, 90(12), p.2467-2472. 31. Ramanaiah, M., Goutham Sri, S. and Sailaja, B.B.V., 2014. Chemical Speciation of Pb(II), Cd(II) and Hg(II) Binary Complexes of L-Phenylalanine in CTAB -Water Mixtures. J. Indian Chem. soc., 91, p.351-357. 32. Seetharam, P., Ramanaiah, M. and Sailaja, B.B.V., 2016. pH- metric Investigation on Binary Complexes of Ca(II), Mg(II) and Zn(II) with Glycylglycine in TX100 – Water Mixtures, Der Pharma Chemica, 8(13), p.91-98. 33. Seetharam, P., Balakrishna, M., Ramanaiah, M. and Sailaja, B.B.V., 2021. Potentiometric Studies on Bioactive Material Species of Ternary Complexes in SLS-Water mixtures, Materials Today: Proceedings, 42, p.3046-3053. 34. Ramanaiah, M., Balakrishna, M., Ramakrishna, B., Venkataramana, M. and Prasada Rao, B.V.V., 2022. Profiling of Trace Elements in Indian Vital Medicinal Plant Momirdica Charantia Using Inductively Coupled Plasma-Mass Spectroscopy. Annals of Forest Research 65(1):3039-3048. 35. Seetharam, P., Ramanaiah, M., RamuNaiudu, P. and Sailaja, B. B. V., 2017. Speciation of Binary Complexes of Ca(II), Mg(II) and Zn (II) with Histamine in CTAB Water Mixtures, Res. J. Pharm. Biol. Chem. Sci., 8 (2), p.1116-1125.
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